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OLKeeper
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| OLKeeper reliably prevents users from closing their Outlook window and thus possibly missing reminders or e-mails. | 
This small sample demonstrates how to get the default account with the Redemption.
Public Function GetDefaultMailAccount() As String
  Dim Session As Redemption.RDOSession
  Dim List As Redemption.RDOAccountOrderList
  Set Session = CreateObject("redemption.rdosession")
  Session.LogOn ""
  ' The first object of the sorted list is always the default account
  Set List = Session.Accounts.GetOrder(acMail)
  GetDefaultMailAccount = List.Item(1).Name
End Function